Titanocene pentasulfide
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| Other names titanocene pentasulfide | |
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| Properties | |
Chemical formula | C10H10S5Ti |
| Molar mass | 338.382 |
| Appearance | red solid |
| Structure | |
Coordination geometry | Dist. tetrahedral |
| Related compounds | |
Related compounds | Zirconocene pentasulfide Titanocene dichloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references | |
Chemical compound
Titanocene pentasulfide is the organotitanium compound with the formula (C5H5)2TiS5, commonly abbreviated as Cp2TiS5. This metallocene exists as a bright red solid that is soluble in organic solvents. It is of academic interest as a precursor to unusual allotropes of elemental sulfur as well as some related inorganic rings.
Preparation and structure
Titanocene pentasulfide is prepared by treating Cp2TiCl2 with polysulfide salts:[1] It was first produced by the addition of elemental sulfur to titanocene dicarbonyl:[2]
- (C5H5)2Ti(CO)2 + 5⁄8 S8 → (C5H5)2TiS5 + 2 CO
The complex is viewed as a pseudotetrahedral complex of Ti(IV). The Ti–S distances are 2.420 and 2.446 Å and the S–S bond distances are of a normal range, 2.051–2.059 Å.[3] The molecule exhibits a dynamic NMR spectrum owing to the chair–chair equilibrium of the TiS5 ring which equivalizes the Cp signals at high temperatures.[4]
Reactions
Cp2TiS5 reacts with sulfur and selenium chlorides, ExCl2, to afford titanocene dichloride and various S5+x and S5Sex rings. Illustrative is the synthesis of S7 from disulfur dichloride:[5]
- (C5H5)2TiS5 + S2Cl2 → (C5H5)2TiCl2 + S7
It also reacts with alkenes and ketenes to give heterocycles composed of Ti, C and S. With trialkylphosphines, the cycle dimerize into rings of various sizes, depending on the trialkylphosphine used.[6]
References
- ^ Shaver, Alan; McCall, James M.; Marmolejo, Gabriela (1990). "Cyclometallapolysulfanes (And Selanes) of Bis(η 5 -Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV)". Inorganic Syntheses. Inorg. Synth. Vol. 27. pp. 59–65. doi:10.1002/9780470132586.ch11. ISBN 978-0-470-13258-6.
- ^ "π-Complexes of Group IVA metals with cyclopentadiene, indene, and fluorine". Bull. Soc. Chim. France. 11: 3548–64. 1966.
- ^ Epstein, E. F.; Bernal, I. (1970). "Pentachalcogenide dianions in transition-metal complexes: crystal structure of bis-(π-cyclopentadienyl)titanium pentasulphide". J. Chem. Soc. D. 1970 (7): 410–411. doi:10.1039/C29700000410.
- ^ Shaver, Alan; McCall, James M. (1984). "Preparation and Variable-Temperature NMR Studies of the Metallacyclosulfanes Cp2MS5 and (MeSCp)MS3, Where M = Ti, Zr, and Hf". Organometallics. 3 (12): 1823–1829. doi:10.1021/om00090a008.
- ^ Steudel, Ralf; Eckert, Bodo (2003). "Solid Sulfur Allotropes Sulfur Allotropes". Topics in Current Chemistry. 230: 1–80. doi:10.1007/b12110.
- ^ Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999). Advanced Inorganic Chemistry (6th ed.). Wiley. ISBN 978-0-471-19957-1.
- v
- t
- e
- TiCl2
- TiH2
- TiBr2
- TiI2
- TiO
- TiS
- TiSi2
| Organotitanium(II) compounds | [(C5H5)2Ti(CO)2] |
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| Organotitanium(III) compounds | [(C5H5)2TiCl]2 |
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- TiB2
- TiBr4
- TiC
- TiS(S2)
- TiCl4
- Ti(ClO4)4
- TiF4
- H2TiF6
- TiH4
- TiI4
- TiOSO4
- Ti(NMe2)4
- Ti(NO3)4
- TiO2
- H4TiO4
- Ti(C2H3O2)4
- Ti4(OCH2CH3)16
- Ti(OCH(CH3)2)4
- Ti(OCH2CH2CH2CH3)4
- KTiOPO4
- NiO·Sb2O3·20TiO2
- TiS2
- TiSe2
- TiSi2
- Ti(C
3H
5O
3)
4
| Titanate compounds |
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| Organotitanium(IV) compounds |
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